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The chemistry and biochemistry of reactive intermediates is central to modern mechanistic and quantitative understanding of organic chemistry and biochemistry. The only comprehensive review to cover carbon-centered radical intermediates and their role(s) in chemistry and biochemistry, Carbon-Centered Radicals provides detailed explanations of the role of these intermediates in organic reactions and detailed discussions of their versatility with respect to functional groups to help graduate students and professional researchers better understand and expand their synthetic utility.