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Neue Ein-Topf-Sequenzen

Auf der Basis cyclisierender Isomerisierungen von In-Allylalkoholen

Language GermanGerman
Book Paperback
Book Neue Ein-Topf-Sequenzen Christoph J. Kressierer
Libristo code: 06813412
Publishers VDM Verlag Dr. Müller, November 2007
In palladium- und rhodiumkatalysierten Alder-En-analogen Reaktionen wurden In-Allylalkohol-Substrate... Full description
? points 203 b
83.99 €
164.27  лв
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In palladium- und rhodiumkatalysierten Alder-En-analogen Reaktionen wurden In-Allylalkohol-Substrate cycloisomerisiert, die dann in einer anschließenden Tautomerie zu den entsprechenden Enalen umlagerten. Daneben wurden in Heck-Carbopalladierungsreaktionen ebenfalls In-Allylalkohole eingesetzt, die in einer Folge aus Carbopalladierung, Heck-Reaktion und anschließender Tautomerie ebenfalls Enale bildeten. Diese so gebildeten Enale wurden als Diversitätsmodule benutzt, um Konsekutivreaktionen im Ein-Topf-Verfahren anzuschließen. Hier konnte eine Reihe von Konsekutivreaktionen durchgeführt werden, darunter Wittig-Olefinierungen, reduktive Aminierungen und Knoevenagel-Kondensationen, die die Diversität und Komplexität der Reaktionsprodukte enorm erhöhten.

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About the book

Full name Neue Ein-Topf-Sequenzen
Author Christoph J. Kressierer
Language German
Binding Book - Paperback
Date of issue 2008
Number of pages 456
EAN 9783639037630
Libristo code 06813412
Publishers VDM Verlag Dr. Müller
Weight 602
Dimensions 154 x 220 x 30
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